Molten salt-assisted synthesis of bismuth nanosheets with long-term cyclability at high rates for sodium-ion batteries
Publication Name
RSC Advances
Abstract
Bismuth is a promising anode material for sodium-ion batteries (SIBs) due to its high capacity and suitable working potential. However, the large volume change during alloying/dealloying would lead to poor cycling performance. Herein, we have constructed a 3D hierarchical structure assembled by bismuth nanosheets, addressing the challenges of fast kinetics, and providing efficient stress and strain relief room. The uniform bismuth nanosheets are prepared via a molten salt-assisted aluminum thermal reduction method. Compared with the commercial bismuth powder, the bismuth nanosheets present a larger specific surface area and interlayer spacing, which is beneficial for sodium ion insertion and release. As a result, the bismuth nanosheet anode presents excellent sodium storage properties with an ultralong cycle life of 6500 cycles at a high current density of 10 A g−1, and an excellent capacity retention of 87% at an ultrahigh current rate of 30 A g−1. Moreover, the full SIBs that paired with the Na3V2(PO4)3/rGO cathode exhibited excellent performance. This work not only presents a novel strategy for preparing bismuth nanosheets with significantly increased interlayer spacing but also offers a straightforward synthesis method utilizing low-cost precursors. Furthermore, the outstanding performance demonstrated by these nanosheets indicates their potential for various practical applications.
Open Access Status
This publication may be available as open access
Volume
13
Issue
36
First Page
25552
Last Page
25560
Funding Number
22272093
Funding Sponsor
National Natural Science Foundation of China