Effect of the Cu2+/1+ Redox Potential of Non-Macrocyclic Cu Complexes on Electrochemical CO2 Reduction
Publication Name
Molecules
Abstract
Cu2+/1+ complexes facilitate the reduction of CO2 to valuable chemicals. The catalytic conversion likely involves the binding of CO2 and/or reduction intermediates to Cu2+/1+, which in turn could be influenced by the electron density on the Cu2+/1+ ion. Herein we investigated whether modulating the redox potential of Cu2+/1+ complexes by changing their ligand structures influenced their CO2 reduction performance significantly. We synthesised new heteroleptic Cu2/1+ complexes, and for the first time, studied a (Cu-bis(8-quinolinolato) complex, covering a Cu2+/1+ redox potential range of 1.3 V. We have found that the redox potential influenced the Faradaic efficiency of CO2 reduction to CO. However, no correlation between the redox potential and the Faradaic efficiency for methane was found. The lack of correlation could be attributed to the presence of a Cu-complex-derived catalyst deposited on the electrodes leading to a heterogeneous catalytic mechanism, which is controlled by the structure of the in situ deposited catalyst and not the redox potential of the pre-cursor Cu2+/1+ complexes.
Open Access Status
This publication may be available as open access
Volume
28
Issue
13
Article Number
5179
Funding Number
CE 140100012
Funding Sponsor
Australian Research Council