Strong tribocatalytic dye degradation by tungsten bronze Ba4Nd2Fe2Nb8O30

Publication Name

Ceramics International

Abstract

The triboelectric effect has recently demonstrated its great potential in environmental remediation and even new energy applications for triggering a number of catalytic reactions by utilizing trivial mechanical energy. In this study, Ba Nd Fe Nb O (BNFN) submicron powders were used to degrade organic dyes via the tribocatalytic effect. Under the frictional excitation of three PTFE stirring rods in a 5 mg/L RhB dye solution, BNFN demonstrates a high tribocatalytic degradation efficiency of 97% in 2 h. Hydroxyl radicals (•OH) and superoxide radicals (•O -) were also detected during the catalysis process, which proves that triboelectric energy stimulates BNFN to generate electron-hole pairs. The tribocatalysis of tungsten bronze BNFN submicron powders provides a novel and efficient method for the degradation of wastewater dye by utilizing trivial mechanical energy. 4 2 2 8 30 2

Open Access Status

This publication is not available as open access

Volume

47

Issue

4

First Page

5038

Last Page

5043

Funding Number

19AA-15

Funding Sponsor

National Natural Science Foundation of China

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Link to publisher version (DOI)

http://dx.doi.org/10.1016/j.ceramint.2020.10.081