Experimental Confirmation of the Universal Law for the Vibrational Density of States of Liquids
Publication Name
Journal of Physical Chemistry Letters
Abstract
An analytical model describing the vibrational density of states (VDOS) of liquids has long been elusive, owing to the complexities of liquid dynamics. Nevertheless, Zaccone and Baggioli have recently developed such a model which was proposed to be the universal law for the vibrational density of states of liquids. Distinct from the Debye law, g(ω) ∝ ω2, for solids, the universal law for liquids reveals a linear relationship, g(ω) ∝ ω, in the low-energy region. We have confirmed this universal law with experimental VDOS measured by inelastic neutron scattering on real liquid systems including water, liquid metal, and polymer liquids, and have applied this model to extract the effective relaxation rate for the short time dynamics for each liquid. The model has also been further evaluated in the prediction of the specific heat with comparison to existing experimental data as well as with values obtained by different approaches.
Open Access Status
This publication may be available as open access
Volume
13
Issue
13
First Page
3105
Last Page
3111
Funding Number
DP210101436
Funding Sponsor
Australian Research Council