In situ synthesis of nanostructured carbon reinforcement in aluminum powders

Authors

Xin Xu, Shanghai Jiao Tong University
Zhiqiang Li, Uni of California
Di Zhang, Shanghai Jiao Tong University, 800 Dongchuan Road, ShanghaiFollow
Zhixin Chen, University of WollongongFollow

RIS ID

33201

Publication Details

Xu, X., Li, Z., Zhang, D. and Chen, Z. (2010). In situ synthesis of nanostructured carbon reinforcement in aluminum powders. Materials Letters, 64 (10), 1154-1156.

Abstract

A novel approach was developed to obtain uniformly dispersed nanostructured carbon reinforcement in aluminum matrix composite powders. This process involves in situ synthesis of carbon nanoflakes (CNFs) with thickness of 30–50 nm on the surface of aluminum powders through Friedel–Crafts alkylation of benzene under its supercritical conditions, at 300 °C and 5.7 MPa with benzene and C₂Cl₆ as carbon sources, and AlCl₃ as catalyst. In this process, all the reactants and catalyst are in gaseous state, which play an important role in inducing homogeneous reaction and dispersion of the CNFs. Meanwhile, Al powders play an important role in inducing the morphology of the CNFs by providing the heterogeneous nucleation sites.