In situ high temperature optical microscopy study of phase evolution in YBa2Cu3O7-δ films prepared by a fluorine-free sol-gel route

Authors

Yinglong Zhang, Shanghai Jiao Tong University, China
X Yao, Shanghai Jiao Tong University, China
J Lian, University of Michigan, USA
L Wang, University of Michigan, USA
Aihua Li, University of WollongongFollow
Hua-Kun Liu, University of WollongongFollow
H Yao, Tsinghua University, China
Z Han, Tsinghua University, China
Laifeng Li, Chinese Academy of Sciences, China
Y Xu, University of Cincinnati, USA
Dongqi Shi, University of WollongongFollow

RIS ID

17984

Publication Details

Zhang, Y, Yao, X, Lian, J, Wang, L, Li, A, Liu, HK, Yao, H, Han, Z, Li, L, Xu, Y & Shi, D (2006), In situ high temperature optical microscopy study of phase evolution in YBa2Cu3O7-δ films prepared by a fluorine-free sol-gel route, Physica C: Superconductivity and its Applications, 436(2), pp. 62-67.

Abstract

Phase evolution of YBa₂Cu₃O_7−δ (YBCO) thin films prepared by a newly-developed fluorine-free sol–gel method were studied by combined use of in situ high temperature optical microscope observation and X-ray diffraction. The reaction sequences associated with yttrium, barium and copper in this route were determined respectively. It was found that the reactions that take place were strongly dependent on the experimental conditions such as water partial pressure. The formation of YBCO started around 710 °C and continued up to 800 °C for about 15 min. The formation mechanism of YBCO was found to be dependent on the barium containing phases, which were controlled by the experimental conditions. The formation of a- and c-axes oriented YBCO grains was also found to be governed by the processing reactions.