Liquid crystalline dispersions of graphene-oxide-based hybrids: a practical approach towards the next generation of 3D isotropic architectures for energy storage applications
RIS ID
89618
Abstract
We report the use of the spray pyrolysis method to design self-assembled isotropic ternary architectures made up of reduced graphene oxide (GO), functionalized multiwalled carbon nanotubes, and nickel oxide nanoparticles for cost-effective high-performance supercapacitor devices. Electrodes fabricated from this novel ternary system exhibit exceptionally high capacitance (2074 Fg−1) due to the highly conductive network, synergistic link between GO and carbon nanotubes and achieving high surface area monodispersed NiO decorated rGO/CNTs composite employing the liquid crystallinity of GO dispersions. To further assess the practicality of this material for supercapacitor manufacture, we assembled an asymmetric supercapacitor device incorporating activated carbon as the anode. The asymmetric supercapacitor device showed remarkable capacity retention (>96%), high energy density (23 Wh kg−1), and a coulombic efficiency of 99.5%.
Grant Number
ARC/DP1093952
Publication Details
Chidembo, A. T., Aboutalebi, S. H., Konstantinov, K., Wexler, D., Liu, H. K. & Dou, S. X. (2014). Liquid crystalline dispersions of graphene-oxide-based hybrids: a practical approach towards the next generation of 3D isotropic architectures for energy storage applications. Particle and Particle Systems Characterization, 31 (4), 465-473.