XRD and Spectroscopic Investigations of ZIF—Microchannel Glass Plates Composites

Publication Name

Materials

Abstract

In this study, new composite materials comprising zeolitic imidazolate framework (ZIF) structures and microchannel glass (MCG) plates were fabricated using the hydrothermal method and their morphological and spectral properties were investigated using XRD, SEM, FTIR, and Raman spectroscopy. XRD studies of powder samples revealed the presence of an additional phase for a ZIF-8 sample, whereas ZIF-67 samples, which were prepared through two different chemical routes, showed no additional phases. A detailed analysis of the FTIR and micro-Raman spectra of the composite samples revealed the formation of stable ZIF structures inside the macropores of the MCG substrate. The hydrophilic nature of the MCG substrate and its interaction with the ZIF structure resulted in the formation of stable ZIF-MCG composites. We believe that these composite materials may find a wide range of important applications in the field of sensors, molecular sieving.

Open Access Status

This publication may be available as open access

Volume

16

Issue

6

Article Number

2410

Funding Number

SFI 16/RC/3889

Funding Sponsor

Science Foundation Ireland

Share

COinS
 

Link to publisher version (DOI)

http://dx.doi.org/10.3390/ma16062410