Title

Magnetic hybrid organic-inorganic perovskite (CH3NH3)2XCl4(X = Mn, Cu, Co) crystals

Publication Name

CrystEngComm

Abstract

For the hybrid organic-inorganic perovskites with the general formula of A2MIIX4(A = methylammonium; MII= Mn, Cu and Co; X = Cl), the arrangement of metal ions and organic ligands leads to a delicate balance of space, spin and charge, which results in diverse properties. In this paper, we reported a group of hybrid organic-inorganic perovskite single crystals of (CH3NH3)2MnCl4, (CH3NH3)2CuCl4and (CH3NH3)2CoCl4grown by a simple solution evaporation method. Magnetic measurements show that all the single crystals display magnetic ordering at low temperature. Our results reveal a novel group of hybrid organic-inorganic magnetic perovskites.

Open Access Status

This publication is not available as open access

Volume

23

Issue

30

First Page

5208

Last Page

5213

Funding Number

Q20201512

Funding Sponsor

Hubei Provincial Department of Education

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Link to publisher version (DOI)

http://dx.doi.org/10.1039/d1ce00679g