Title

Wireless electrochemiluminescence at functionalised gold microparticles using 3D titanium electrode arrays

Publication Name

Chemical Communications

Abstract

Wireless electrochemiluminescence is generated using interdigitated, 3D printed, titanium arrays as feeder electrodes to shape the electric field. Gold microparticles (45 μm diameter), functionalised with 11-mercaptoundecanoic acid, act as micro-emitters to generate electrochemiluminescence from [Ru(bpy)3]2+, (bpy is 2,2′-bipyridine) where the co-reactant is tripropylamine. The oxide coated titanium allows intense electric fields, whose distribution depends on the geometry of the array, to be created in the absence of deliberately added electrolyte. COMSOL modelling and long exposure ECL imaging have been used to map the electric field distribution. Significantly, we demonstrate that by controlling the surface charge of the gold microparticles through the solution pH, the light intensity can be increased by a factor of more than 10. This journal is

Open Access Status

This publication is not available as open access

Volume

57

Issue

38

First Page

4642

Last Page

4645

Funding Number

CE140100012

Funding Sponsor

Australian National Fabrication Facility

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Link to publisher version (DOI)

http://dx.doi.org/10.1039/d1cc01010g