RIS ID

144107

Publication Details

Ablott, T., Fishburn, M., Turner, D. & Richardson, C. (2020). Intramolecular interception of the Newman-Kwart rearrangement by carboxylic acids. Tetrahedron Letters,

Abstract

© 2020 Elsevier Ltd Instead of undergoing the Newman-Kwart rearrangement, thermally-promoted reactions of O-aryl dimethylthiocarbamates featuring ortho-carboxylic acid substituents result in the loss of carbonylsulfide and formation of N,N-dimethylsalicylamides in high yields.

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Link to publisher version (DOI)

http://dx.doi.org/10.1016/j.tetlet.2020.152153