Understanding the ground- and excited-state photophysics of oxadiazole and triarylamine substituents in copper and rhenium metal complexes

Authors

Rachel Horvarth, University of Otago
Michael Fraser, University of Otago
Pawel W. Wagner, University of WollongongFollow
David L. Officer, University of WollongongFollow
Keith C. Gordon, Otago University

RIS ID

44151

Publication Details

Horvarth, R., Fraser, M., Wagner, P. W., Officer, D. L. & Gordon, K. C. (2010). Understanding the ground- and excited-state photophysics of oxadiazole and triarylamine substituents in copper and rhenium metal complexes. AIP Conference Proceedings, 1267 (1), 297-298.

Abstract

The article presents information on a study conducted on rhenium and copper complexes, [Cu(L)(PPh3)]+ and [Re(L)(CO)3Cl]. The properties of ground and excited states of these complexes have been studied using methods like the Raman affect. The orbital energies of the molecular orbitals which are linked with triarylamine groups experience an increase.