posted on 2024-11-15, 05:05authored byAnthony Wright, T E O'Brien, Chao ZhangChao Zhang, Dieter Beaven
We demonstrate two unusual electronic properties of semihydrogenated graphene with variable sized A- or B-hydrogenated domains within the tight-binding formalism as follows: (i) a universal band gap scaling law which states that the band gap depends linearly upon the ratio of the number of A- to B-hydrogenated atoms, NA/NB, reaching zero gap at NA = NB, but independent of the domain size, and (ii) an insulating state with zero band gap at NA = NB, a rare phenomenon in nature. We confirm this gapless insulator state by the zero optical conductance at low frequencies.
History
Citation
Wright, A., O'Brien, T. E., Beaven, D. and Zhang, C. (2010). Gapless insulator and a band gap scaling law in semihydrogenated graphene. Applied Physics Letters, 97 (4), 043104-1-043104-3.