posted on 2024-11-14, 14:46authored byAndrew D Burrows, Christopher G Frost, Mary F Mahon, Paul R Raithby, Catherine L Renouf, Christopher RichardsonChristopher Richardson, Anna J Stevenson
The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.
History
Citation
Burrows, A. D., Frost, C., Mahon, M. F., Raithby, P. R., Renouf, C., Richardson, C. & Stevenson, A. (2010). Dipyridyl beta-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks. Chemical Communications, 46 (28), 5067-5069.