Title

Enhanced pyroelectric and piezoelectric responses in W/Mn-codoped Bi4Ti3O12Aurivillius ceramics

RIS ID

129873

Publication Details

Tang, Y., Shen, Z., Du, Q., Zhao, X., Wang, F., Qin, X., Wang, T., Shi, W., Sun, D., Zhou, Z. & Zhang, S. (2018). Enhanced pyroelectric and piezoelectric responses in W/Mn-codoped Bi4Ti3O12Aurivillius ceramics. Journal of the European Ceramic Society, 38 (16), 5348-5353.

Abstract

The pyroelectric and piezoelectric properties of 4 at% Mn-doped Bi4Ti2.9W0.1O12(BiTW-Mn) Aurivillius ceramic were investigated and compared to Bi4Ti2.9W0.1O12(BiTW) counterpart, which were fabricated using a conventional solid state reaction method. High resistivities of 4.9 x 1012and 2.5 x 1011Ω cm at 100 °C were obtained in the W-doped and W/Mn-codoped BiT ceramics, respectively. They showed similar activation energies and ionic-p-type mixed conduction mechanisms. Higher pyroelectric coefficients of 57.1 μC/m2K and piezoelectric coefficients of 21 pC/N, as well as much lower dielectric loss of 0.003 were achieved in W/Mn-codoped ceramics. These property changes were mainly induced by MnTi−Vodefect dipoles. The effect of acceptor doping was evidenced by an internal bias field, shown by a horizontal offset in the polarization-field behavior. The improved properties together with high thermal stability indicate that BiTW-Mn may be a promising candidate for pyroelectric and piezoelectric devices at elevated temperatures.

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