Title

Synthesis, characterization, and structures of a persistent aniline radical cation

RIS ID

108767

Publication Details

Chen, X., Wang, X., Sui, Y., Li, Y., Ma, J., Zuo, J. & Wang, X. (2012). Synthesis, characterization, and structures of a persistent aniline radical cation. Angewandte Chemie International Edition, 51 (47), 11878-11881.

Abstract

Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6-tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long C-N bond beyond theoretical prediction.

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Link to publisher version (DOI)

http://dx.doi.org/10.1002/anie.201205478