Title

Two phosphaalkene radical cations with inverse spin density distributions

RIS ID

108672

Publication Details

Pan, X., Wang, X., Zhang, Z. & Wang, X. (2015). Two phosphaalkene radical cations with inverse spin density distributions. Dalton Transactions: an international journal of inorganic chemistry, 44 (34), 15099-15102.

Abstract

Two phosphaalkene radical cations 1•+ and 2•+ have been reported. 1•+ is stable in the solid state and has been structurally characterized. 2•+ only remains persistent in solution. 1•+ is described as a phosphorus-centered radical, while 2•+ as a delocalized radical with little contribution from phosphorus.

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Link to publisher version (DOI)

http://dx.doi.org/10.1039/c5dt00656b