Synthesis of chiral allylic amines via palladium(0) catalysed allylations of allylic carbonates with chiral sulfinamide anions

Authors

Zemin Dong, University of Wollongong
Stephen G. Pyne, University of WollongongFollow

RIS ID

8002

Publication Details

Dong, Z. & Pyne, S. G. (2002). Synthesis of chiral allylic amines via palladium(0) catalysed allylations of allylic carbonates with chiral sulfinamide anions. Sulfur Letters, 25 (1), 37-43.

Abstract

The palladium(0) catalysed allylation reactions of allylic carbonates with chiral sulfinamide anions to give unstable allylic sulfinamide products are described. These products are readily converted to stable, chiral N-benzoyl or N-tosyl allylic amine derivatives with poor to modest enantiomeric purities (ee 23-41%).