Title

La2Co2Se2O3: a quasi-two-dimensional mott insulator with unusual cobalt spin state and possible orbital ordering

RIS ID

69952

Publication Details

Wang, C., Tan, M., Feng, C., Ma, Z., Jiang, S., Xu, Z., Cao, G., Matsubayashi, K. & Uwatoko, Y. (2010). La2Co2Se2O3: a quasi-two-dimensional mott insulator with unusual cobalt spin state and possible orbital ordering. Journal of the American Chemical Society, 132 (20), 7069-7073.

Abstract

The new oxyselenide La2Co2Se2O3, containing Co2O square-planar layers, has been successfully synthesized using solid-state reactions under vacuum. The compound crystallizes in space group I4/mmm with lattice parameters a = 4.0697(8) Å and c = 18.419(4) Å. Magnetic susceptibility measurements indicate an antiferromagnetic transition at 220 K. The magnetic entropy associated with the transition is close to R ln 2, suggesting an unusual low-spin state for the Co2+ ions. The as-prepared sample shows insulating behavior with room-temperature resistivity of 107 Ω cm, which decreases by 4 orders of magnitude under a pressure of 7 GPa. Band structure calculations using the LSDA+U approach reproduce the insulating ground state with low spin for Co and suggest strong orbital polarization for the valence electrons near the Fermi level. It is also revealed that the spin and orbital degrees of freedom in the antiferromagnetic checkerboard spin−lattice are mutually coupled.

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Link to publisher version (DOI)

http://dx.doi.org/10.1021/ja1001295