A Sn-Sn02/C nanocomposite was synthesized using the electrospinning method. Thermal analysis was used to determine the content range of Sn and Sn02 in the composite. The composite was characterized by X-ray diffraction, and the particle size and shape in the Sn-SnOiC composite were determined by scanning and transmission electron microscopy. The results show that the Sn-Sn02/C composite takes on a nanofiber morphology, with the diameters of the nanofibers distributed from 50 to 200 nm. The electrOChemical properties of the Sn-SnOiC composite were also investigated. The Sn-SnOiC composite as an electrode material has both higher reversible capacity (887 mAh· g-I). and good cycling performance in lithium-anode ceUs working at room temperature in a 3.0 V to O.Ot V potential window. The Sn-Sn02/C composite could relain a discharge capacity of 546 mAWg aller 30 cycles. The outstanding electrochemical properties of the Sn-SnOiC composite oblained by this method make it possible for Ihis composite to be used as a promising anode material.