RIS ID

82372

Publication Details

Baek, W., Arndt, A., Bug, M. & Wang, M. (2013). Total electron-scattering cross sections of pyrimidine. Physical Review A: Atomic, Molecular and Optical Physics, 88 (3), 032702-1-032702-8.

Abstract

Total electron-scattering cross sections of pyrimidine, the basic component for the nucleic bases cytosine and thymine, were measured for electron energies from 5 eV to 1 keV using the linear transmission method. The measured results were compared to semiempirical data obtained by means of the additivity rule and to experimental data for benzene since it has a similar ring structure and the same number of valence electrons as pyrimidine. Furthermore, integral elastic and inelastic electron-scattering cross sections of pyrimidine were calculated by applying the spherical complex optical potential model. The sum of both cross sections agrees reasonably well with the experimental total electron-scattering cross sections of pyrimidine in the energy range from 20 eV to 1 keV. The experimental data are, however, significantly lower than the theoretical cross sections when including the contribution of rotational excitations to the electron scattering.

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Link to publisher version (DOI)

http://dx.doi.org/10.1103/PhysRevA.88.032702