The effect of transition metals on hydrogen migration and catalysis in cast Mg-Ni alloys
The inexpensive fabrication technique of casting is applied to develop new Mg-Ni based hydrogen storage alloys with improved hydrogen sorption properties. A nanostructured eutectic Mg-Mg2Ni is formed upon solidification which introduces a large area of interfaces along which hydrogen diffusion can occur with high diffusivity. After a few cycles of hydrogenation and dehydrogenation, an ultrafine porous structure formed in the eutectic Mg-Mg2Ni and some cracks developed along the interface between the eutectic and the a-Mg matrix. This indicates that hydrogen atoms introduced into the alloys preferentially migrate along the interfaces in the nanostructured eutectic which enables effective short-range diffusion of hydrogen. Furthermore, transition metals (TMs) such as Nb, Ti and V in the range 240e560 ppm are added directly to molten Mg-10 wt% Ni alloys and are found to form intermetallic compounds with Ni during solidification. The alloys can store 5.6e6.3 wt% hydrogen at 350 0C and 2 MPa. TM-rich intermetallics distributed homogeneously in the cast alloys appear to play a key role in accelerating the nucleation of Mg from MgH2 upon dehydrogenation. This leads to a significant improvement in the hydrogen desorption kinetics.
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