Title

Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

RIS ID

114495

Publication Details

Li, L., Zhang, Y., Avdeev, M., Lindoy, L. F., Harman, D. G., Zheng, R., Cheng, Z., Aldrich-Wright, J. R. & Li, F. (2016). Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage. Dalton Transactions: an international journal of inorganic chemistry, 45 9407-9411.

Abstract

We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12·χsolvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(III) metalloligand and Cu(II) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.

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Link to publisher version (DOI)

http://dx.doi.org/10.1039/C6DT01651K