RIS ID

104253

Publication Details

Park, H. S., Lee, C. & Reisner, E. (2014). Photoelectrochemical reduction of aqueous protons with a CuO|CuBi2O4 heterojunction under visible light irradiation. Physical Chemistry Chemical Physics, 16 (41), 22462-22465.

Abstract

A p-type heterojunction photoelectrode consisting of platinized CuBi2O4 layered on a CuO film was prepared. The CuO|CuBi2O4|Pt electrode photo-generates H2 in pH neutral aqueous solution during visible light irradiation and exhibits a substantially enhanced photocurrent compared to CuO|Pt and CuBi2O4|Pt electrodes. Reduced electron-hole recombination by the band offsets in the heterostructure is responsible for the improved photoelectrochemical performance of CuO|CuBi2O4 with a small band-gap of approximately 1.5 eV.

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Link to publisher version (DOI)

http://dx.doi.org/10.1039/c4cp03883e