Title

Electrochemically induced synthesis of poly(2,6-carbazole)

RIS ID

102185

Publication Details

Laba, K., Data, P., Zassowski, P., Karon, K., Lapkowski, M., Wagner, P., Officer, D. L. & Wallace, G. G. (2015). Electrochemically induced synthesis of poly (2,6-carbazole). Macromolecular Rapid Communications, 36 (19), 1749-1755.

Abstract

The formation of a poly(2,6-carbazole) derivative during an electrochemical polymerization process is shown. Comparison of 3,5-bis(9-octyl-9H-carbazol-2-yl)pyridine and 3,5-bis(9-octyl-9H-carbazol-3-yl)pyridine by electrochemical and UV-Vis-NIR spectroelectrochemical measurements and DFT (density functional theory) calculation prove the formation of a poly(2,6-carbazole) derivative. Both of the compounds form stable and electroactive conjugated polymers.

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Link to publisher version (DOI)

http://dx.doi.org/10.1002/marc.201500260