2-(10′,10′-Dimethyl-3′-sulfanylidene-4′- azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4- azatricyclo[5.2.1.01,5]decane-3-thione

Authors

Ashley Walker, Monash UniversityFollow
Craig M. Forsyth, Monash University
Patrick Perlmutter, Monash University

RIS ID

101541

Publication Details

Walker, A., Forsyth, C. M. & Perlmutter, P. (2013). 2-(10′,10′-Dimethyl-3′-sulfanylidene-4′- azatricyclo[5.2.1.0^1,5]decan-2′-yl)-10,10-dimethyl-4- azatricyclo[5.2.1.0^1,5]decane-3-thione. Acta Crystallographica Section E: Structure Reports Online, E69 (8), o1282-1-o1282-7.

Abstract

The title compound, C₂₈H₄₀N₂O₂S₂, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionyl­thiol­actam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C-C bond with a C-C-C-C- torsion angle of 20.4 (3)°.