RIS ID

101010

Publication Details

Chen, X., Li, Z. & Dou, S. Xue. (2015). Ambient facile synthesis of gram-scale copper selenide nanostructures from commercial copper and selenium powder. ACS Applied Materials and Interfaces, 7 (24), 13295-13302.

Abstract

Grams of copper selenides (Cu2-xSe) were prepared from commercial copper and selenium powders in the presence of thiol ligands by a one-pot reaction at room temperature. The resultant copper selenides are a mixture of nanoparticles and their assembled nanosheets, and the thickness of nanosheets assembled is strongly dependent on the ratio of thiol ligand to selenium powder. The resultant Cu2-xSe (0 ≤ x ≤ 0.25) nanostructures were treated with hydrazine solution to remove the surface ligands and then explored as a potential thermoelectric candidate in comparison with commercial copper selenide powders. The research provides a novel ambient approach for preparation of Cu2-xSe nanocrystallines on a large scale for various applications.

Grant Number

ARC/LE120100104, ARC/LP120200289, ARC/DP130102699, ARC/DP130102274

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Link to publisher version (DOI)

http://dx.doi.org/10.1021/acsami.5b01085